abiosus e.V. Conferences

Plant oils as precursors of N-containing compounds via alkene metathesis

Abstract submitted to "2nd Workshop on Fats and Oils as Renewable Feedstock for the Chemical Industry "
Plant oils as precursors of N-containing compounds via alkene metathesis
Christian Bruneau
Institut Sciences Chimiques de Rennes - Catalyse et Organométalliques,
Pierre H. Dixneuf
Institut Sciences Chimiques de Rennes - Catalyse et Organométalliques,
Raluca Malacea
Institut Sciences Chimiques de Rennes - Catalyse et Organométalliques,
Cédric Fischmeister
Institut Sciences Chimiques de Rennes - Catalyse et Organométalliques,
Xiaowei Miao
Institut Sciences Chimiques de Rennes - Catalyse et Organométalliques,
Keywords:
Presentation preference: oral

Plant oils, the known precursors of a variety of unsaturated acid derivatives have also the potential to produce, by action of alkene metathesis catalysis, new intermediates useful for chemical industry, from renewable materials.
The cross-metathesis, promoted by selected ruthenium catalysts, of unsaturated esters, acids and other oil derivatives with acrylonitrile and fumaronitrile will be presented [1]


The formed bifunctional compounds are thus the precursors of linear aminoacids and thus polyamides.

[1] R. Malacea et al, Green Chem., 2009, 11, 152-155

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